Article: Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes (Shampa)
 

[B]Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes[/B]

Organometallics 2008, 27, 1026–1027

Vo D. M. Hoang, Pattubala A. N. Reddy, and Tae-Jeong Kim

Summary: The chiral (iminophosphoranyl)ferrocenes 1-3 are highly Versatile ligands in Cu-catalyzed asymmetric allylic oxidation of a series of cyclic olefins with tert-butyl perbenzoate, achieVing almost complete enantioselectiVity (up to 99% ee) in a reasonably short period of time (36 h).

[URL="http://chemvn.net/library/Vo%20Do%20Minh%20Hoang%20-%20Shampa/Asymmetric%20Allylic%20Oxidation%20Catalyzed%20by%20Copper%28I%29%20Complexes%20of%20Chiral%20%28Iminophosphoranyl%29ferrocenes.pdf"]Download[/URL]