Article: Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes (Shampa)

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Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes

Organometallics 2008, 27, 1026–1027

Vo D. M. Hoang, Pattubala A. N. Reddy, and Tae-Jeong Kim

Summary: The chiral (iminophosphoranyl)ferrocenes 1-3 are highly Versatile ligands in Cu-catalyzed asymmetric allylic oxidation of a series of cyclic olefins with tert-butyl perbenzoate, achieVing almost complete enantioselectiVity (up to 99% ee) in a reasonably short period of time (36 h).

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