reversible tranfer catalysed polymerization là mọt loại phản ứng trùng hợp đặc biệt có xúc tác tạo ra polymer có trọng lượng phân tử đề hơn và nhỏ hơn sơ với polymer đi từ phản ứng trùng hợp cổ điển. Polymer vẫn có thể là polystyrene, polyehtylene,polymethamethylcrylate (PMMA),Polyvinylacetate (PVAc),...
Lĩnh vực này cũng là rất mở nên câu hỏi bạn đưa ra cần cụ thể là loại monomer nào, polymer nào, xúc tác nào là hướng nghiên cứu nhắm đến của bạn.
Vì là lĩnh vực mở, tôi thấy có rất nhiều đề tài, thông tin trên mạng. Bạn nên tra cứu và chuẩn bị trước khi hỏi. cái gì là bạn cần mà không thể có hoặc cái gì bạn có mà bạn chưa có hiểu cụ thể?
-http://en.wikipedia.org/wiki/Living_polymerization
-Goto A, Tsujii Y, Fukuda T , Reversible Chain Transfer Catalyzed Polymerization (RTCP): A New Class of Living Radical Polymerization Polymer 49, in press (2008) (Feature Article).
-Goto A, Zushi H, Hirai N, Wakada T, Tsujii Y, Fukuda T, Living Radical Polymerization with Nitrogen Catalyst – Reversible Chain Transfer Catalyzed Polymerization (RTCP) with N-Iodosuccinimide Macromolecules 41, 6261-6263 (2008)
-Kayahara E, Yamago S, Kwak Y, Goto A, Fukuda T , Substituent Effects of Radical-Mediated Organotellanyl Group Transfer Reactions. Optimization of Promoters for Highly Controlled Living Radical Polymerizations Macromolecules 41, 527-529 (2008)
-Goto A, Hirai N, Tsujii Y, Fukuda T, Reversible Transfer Catalyzed Polymerizations (RTCPs) of Styrene and Methyl Methacrylate wit Phosphorus Catalysts Macromol. Symp. 261, 18-22 (2008)
-Goto A, Zushi H, Hirai N, Wakada T, Tsujii Y, Fukuda T, Living Radical Polymerizations with Germanium, Tin, and Phosphorus Catalysts – Reversible Chain Transfer Catalyzed Polymerizations (RTCPs) J. Am. Chem. Soc. 129, 13347-13354 (2007)
-Yoshikawa C, Goto A, Tsujii Y, Ishizuka N, Nakanishi K, Fukuda T, Surface Interaction of Well-Defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes with Proteins J. Polym. Sci. Part A, Polym. Chem. 45, 4795-4803 (2007)
-Goto A, Zushi H, Hirai N, Wakada T, Kwak Y, Fukuda T, Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene and Methacrylates Macromol. Symp. 248, 126-131 (2007)
-Yoshikawa C, Goto A, Ishizuka N, Nakanishi K, Kishida A, Tsujii Y, Fukuda T, Size-Exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization Macromol. Symp. 248, 189-198 (2007)
Goto A, Scaiano JC, Maretti L, Photolysis of an Alkoxyamine Using Intramolecular Energy Transfer from a Quinoline Antenna – Towards Photo-Induced Living Radical Polymerization Photochem. Photobio. Sci. 6, 833-835 (2007)
-Kwak Y, Tezuka M, Goto A, Fukuda T, Yamago S, Kinetic Study on Role of Ditelluride for Organotellurium-Mediated Living Radical Polymerization (TERP) Macromolecules 40, 595-603 (2007)
-Yamago S, Kayahara E, Kotani M, Ray B, Kwak Y, Goto A, Fukuda T, Highly Controlled Living Radical Polymerization through Dual Activation of Organobismuthines Angew. Chem. Int. Ed. 46, 1304-1306 (2007)
-Goto A, Zushi H, Kwak Y, Fukuda T, Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene ACS Symp. Ser. 944, 595-603 (2006)
-Kwak Y, Goto A, Fukuda T, Kobayashi Y, Yamago S, A systematic Study on Activation Processes in Organotellurium-Mediated Living Radical Polymerizations (TERPs) of Styrene, Methyl Methacrylate, Methyl Acrylate, and Vinyl Acetate Macromolecules 39, 2284-2290 (2006)
-Yoshikawa C, Goto A, Tsujii Y, Fukuda T, Kimura T, Yamamoto K, Kishida A, Protein Repellency of Well-Defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes by Size-Exclusion Effect Macromolecules 39, 4671-4679 (2006)
-Barner-Kowollik C, Buback M, Charleux B, Coote M L, Drache M, Fukuda T, Goto A, Klumperman B, Lowe A B, Mcleary J B, Moad G, Monterio M J, Sanderson R D, Tonge M P, Vana P, Mechanism and Kinetics of Dithiobenzoate-Mediated RAFT Polymerization. 1. The Current Situation J. Polym. Sci. Part A, Polym. Chem. 44, 5809-5831 (2006)
Tsujii Y, Ohno K, Yamamoto S, Goto A, Fukuda T, Structure and Properties of High-Density Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization Adv. Polym. Sci. 197, 1-45 (2006).
-Kubo K, Goto A, Sato K, Kwak Y, Fukuda T, Kinetic Study on Reversible Addition-Fragmentation Chain Transfer (RAFT) Process for Block and Random Copolymerizations of Styrene and Methyl Methacrylate Polymer 46, 9762-9768 (2005)
-Barner-Kowollik C, Buback M, Egorov M, Fukuda T, Goto A, Olja O F, Russell G T, Vana P, Yamada B, Zetterlund P B, Critically Evaluated Termination Rate Coefficients for Free-Radical Polymerization: Experimental Methods Prog. Polym. Sci. 30, 605-643 (2005).
Yoshikawa C, Goto A, Tsujii Y, Fukuda T, Yamamoto K, Kishida A, Fabrication of High-Density Polymer Brush on Polymer Substrate by Surface-Initiated Living Radical Polymerization Macromolecules 38, 4604-4610 (2005)
-Kwak Y, Goto A, Fukuda T, Yamago S, Ray B, Mechanism and Kinetics of Organostibine-Mediated Living Radical Polymerization of Styrene Z. Chem. Phys. 219, 283-294 (2005).
Norisuye T, Morinaga T, Tang-Cong-Miyata Q, Goto A, Fukuda T, Shibayama M, Comparison of the Gelation Dynamics for Polystyrenes Prepared by Conventional and Living Radical Polymerizations: A Time-Resolved Dynamic Light Scattering Study Polymer 46, 1982-1994 (2005).
-Yamago S, Ray B, Iida K, Yoshida J, Tada T, Yoshizawa K, Kwak Y, Goto A, Fukuda T, Highly Versatile Organostibine Mediators for Living Radical Polymerization J. Am. Chem. Soc. 126, 13908-13909 (2004).
-Kwak Y, Goto A, Komatsu K, Sugiura Y, Fukuda T, Characterization of Low-Mass Model 3-Arm Stars Produced in Reversible Addition-Fragmentation Chain Transfer (RAFT) Process Macromolecules 37, 4434-4440 (2004)
Goto A, Fukuda T, Kinetics of Living Radical Polymerization Prog. Polym. Sci. 29, 329-385 (2004)
-Kwak Y, Goto A, Fukuda T, Rate Retardation in Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization: Further Evidence for Cross-Termination Producing 3-Arm Star Chain Macromolecules 37, 1219-1225 (2004)
Wang A R, Zhu S, Kwak Y, Goto A, Fukuda T, Monteiro M S, A Difference of Six Orders of Magnitude: A Reply to ¡ÈThe Magnitude of Fragmentation Rate Coefficient J. Polym. Sci. Polym. Chem 41, 2833-2839 (2003)
-Goto A, Kwak Y, Fukuda T, Yamago S, Iida K, Nakajima M, Yoshida J, Mechanism-Based Invention of High-Speed Living Radical Polymerization Using Organotellurium Compounds and Azo-Initiators J. Am. Chem. Soc. 125, 8720-8721 (2003)
Fukuda T, Yoshikawa C, Kwak Y, Goto A, Tsujii Y, Mechanisms and Kinetics of Living Radical Polymerization: Absolute Comparison of Theory and Experiment ACS Symp. Ser. 854, 24-40 (2003)
-Yoshikawa C, Goto A, Fukuda T, Quantitative Comparison of Theory and Experiment on Living Radical Polymerization Kinetics. 2. Atom Transfer Radical Polymerization Macromolecules 36, 908-912 (2003)
-Yoshikawa C, Goto A, Fukuda T, Quantitative Comparison of Theory and Experiment on Living Radical Polymerization Kinetics. 1. Nitroxide-Mediated Polymerization Macromolecules 35, 5801-5807 (2002)
Goto A, Kwak Y, Yoshikawa C, Tsujii Y, Sugiura Y, Fukuda T, Comparative Study on Decomposition Rate Constants for Some Alkoxyamines Macromolecules 35, 3520-3525 (2002)
-Kwak Y, Goto A, Tsujii Y, Murata Y, Komatsu K, Fukuda T, A Kinetic Study on the Rate Retardation in Radical Polymerization of Styrene with Addition-Fragmentation Chain Transfer Macromolecules 35, 3026-3029 (2002)
Yoshikawa C, Goto A, Fukuda T, Reactions of Polystyryl Radicals in A Monomer-Free Atom Transfer Radical Polymerization System e-Polymers;
http://www.e-polymers.org No. 13, 1-12 (2002)
-Fukuda T, Goto A, Kwak Y, Ma Y -D, Penultimate Unit Effects in Free Radical Copolymerization Macromol. Symp. 182, 53-64 (2002)
-Fukuda T, Goto A, Tsujii Y, Kinetics of Living Radical Polymerization, In Handbook of Radical Polymerization, K. Matyjaszewski, T. P. Davis, Ed., John Wiley & Sons, New York Chapter 9, 407-462 (2002)
-Goto A, Yoshikawa C, Fukuda T, Quantitative Comparison of Kinetic Theory and Experiment on Living Radical Polymerizations Proceedings of The Sixth International Symposium Organized by Institute for Chemical Research (ICR), Kyoto University , 135-138 (2002)
-Tsujii Y, Ejaz M, Sato K, Goto A, Fukuda T, Mechanism and Kinetics of RAFT-Mediated Graft Polymerization of Styrene on a Solid Surface. 1. Experimental Evidence of Surface Radical Migration Macromolecules 34, 8872-8878 (2001).
-Goto A, Sato K, Fukuda T, Moad G, Rizzardo E, Thang S H, Mechanism and Kinetics of RAFT-Based Polymerizations of Styrene and Methyl Methacrylate Macromolecules 34, 402-408 (2001).
-Fukuda T, Goto A, Ohno K, (Feature Article)Mechanisms and Kinetics of Controlled Radical Polymerizations Macromol. Rapid Commun. 21, 151-165 (2000).
Goto A, Fukuda, Comparative Study on Activation Rate Constants for Some Styrene/Nitroxide Systems Macromol. Chem. Phys. 201, 2138-2142 (2000).
-Fukuda T, Goto A, Kinetics of Living Radical Polymerization ACS Symp. Ser. 768, 27-38 (2000).
-Goto A, Tsujii Y, Fukuda T, Effects of Acetic Anhydride on the Activation and Polymerization Rates in Nitroxide-Mediated Polymerization of Styrene Chem. Lett. 788-789 (2000).
-Goto A, Fukuda T, Kinetic Study on Nitroxide-Mediated Free Radical Polymerization of tert-Butyl Acrylate Macromolecules 32, 618-623 (1999).
-Goto A, Fukuda T, Determination of the Activation Rate Constants of Alkyl Halide Initiators for Atom Transfer Radical Polymerization Macromol. Rapid Commun. 20, 633-636 (1999).
-Goto A, Ohno K, Fukuda T, Mechanism and Kinetics of Iodide-Mediated Polymerization of Styrene Macromolecules 31, 2809-2814 (1998).
Ohno K, Goto A, Fukuda T, Xia J, Matyjaszewski K, Kinetic Study on the Activation Process in an Atom Transfer Radical Polymerization Macromolecules 31, 2699-2701 (1998).
-Fukuda T, Goto A, Ohno K, Tsujii Y, Mechanism and Kinetics of Nitroxide-Controlled Free Radical Polymerization ACS Symp. Ser. 685, 180-199 (1998).
Goto A, Fukuda T, Mechanism and Kinetics of Activation Processes in a Nitroxyl-Mediated Polymerization of Styrene Macromolecules 30, 5183-5186 (1997).
-Goto A, Fukuda T, Effects of Radical Initiator on Polymerization Rate and Polydispersity in Nitroxide-Controlled Free Radical Polymerization Macromolecules 30, 4272-4277 (1997).
-Goto A, Terauchi T, Fukuda T, Miyamoto T, Gel Permeation Chromatographic Determination of Activation Rate Constants in Nitroxide-Controlled Free Radical Polymerization, 1 Direct Analysis by Peak Resolution Macromol. Rapid Commun. 18, 673-682 (1997).
-Fukuda T, Goto A, Gel Permeation Chromatographic Determination of Activation Rate Constants in Nitroxide-Controlled Free Radical Polymerization, 2 Analysis of Evolution of Polydispersities Macromol. Rapid Commun. 18, 683-688 (1997).
-Fukuda T, Terauchi T, Goto A, Ohno K, Tsujii Y, Miyamoto T, Kobatake S, Yamada B, Mechanism and Kinetics of Nitroxide-Controlled Free Radical Polymerization Macromolecules 29, 6393-6398 (1996).
-Fukuda T, Terauchi T, Goto A, Tsujii Y, Miyamoto T, Shimizu Y, Well-Defined Block Copolymers Comprising Styrene-Acrylonitrile Random Copolymer Sequences Synthesized by "Living" Radical Polymerization Macromolecules 29, 3050-3052 (1996).
-Nicolaÿ, R.; Kwak, Y.; Matyjaszewski, K. “Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter” Chemical Communication 2008, ASAP. 0
- Kwak, Y.; Nicolaÿ, R.; Matyjaszewski, K. “Concurrent ATRP/RAFT of Styrene and Methyl Methacrylate with Dithioesters Catalyzed by Copper(I) Complexes” Macromolecules 2008, 41,6602. 0
-Kwak, Y.; Matyjaszewski, K. “Effect of Initiator and Ligand Structures on ATRP of Styrene and Methyl Methacrylate Initiated by Alkyl Dithiocarbamate” Macromolecules 2008, 41, 6627
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